Page 75 - Zmist-n4-2015
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tation of structural units, and from this point the following increment of plastic strain
                  only reduces the parameter y.
                      Considering the wires suffering hydrogenation it was easy to note that fracture in
                  all cases took place before reaching s UTS, obviously, due to rapid growth of a macro-
                  crack. Therefore it could be assumed that values of rupture stress and stress for crack
                                                                     H
                  initiation were very close, the corresponding strain values e u being slightly less than
                   H
                                                H
                                           H
                  e . It could be accepted that e u = e  to simplify the calculation. Then according to (1),
                  curve 4 in Fig. 2, demonstrating the resistance of the investigated steels to initiation of
                  hydrogen induced cracking, was obtained. The curve exhibited maximum in the middle
                  stage of cold drawing, caused by a combined action of two competitive effects. Some
                  retardation  of  crack  initiation  from  the  surface  could  be  a  result  of  reduced  surface
                  roughness as a result of cold drawing. Meanwhile, susceptibility to hydrogen assisted
                  cracking prevails at the final stages because of considerable increment in steel strength.
                  Obviously, surface roughness doesn’t matter in the case of fracture in air, therefore the
                  parameter y u decreases sequentially with cold drawing degree (Fig. 2, curve 2). Con-
                                                                                 H
                                                                                      H
                  cerning the resistance to crack propagation under cathodic polarization y  – y u (see
                  Fig. 2, curves 3 and 4), it should be noted that evolution of this parameter due to cold
                  drawing is similar in both experimental conditions (air and hydrogenation) – it rises
                  slightly at the later stages of cold drawing process. Another situation could be expected
                  for the final prestressing steel (which is not considered in the present work) due to its
                  extremely high strength and essential susceptibility to hydrogen embrittlement [7].
                      Examples of typical fracture maps after both tests (in air and under cathodic pola-
                  rization) are presented in Fig. 3. Three characteristic zones should be distinguished on
                  the fracture surface of the specimen broken in air: a central zone, an intermediate zone
                                                                    and  a  shear  lip.  For  the
                                                                    hydrogenated  specimen  all
                                                                    three  zones  were  also  pre-
                                                                    sent.  Besides,  a  new  zone
                                                                    appeared,  called  tearing
                                                                    topography  surface  (TTS),
                                                                    and  reported  previously  in
                                                                    [9],  which  is  situated  near
                                                                    the lateral surface and indi-
                                                                    cates the place of crack ini-
                                                                    tiation. In both cases radial
                     Fig. 3. Microfracture maps of steel E4 after tensile test
                                                                    marks  in  the  intermediate
                       in air (a) and under hydrogenation in the solution
                     containing1 g/l Ca(OH) 2  + 0.1 g/l NaCl, pH 12.5 (b).   zone  were  observed  which
                                                                    indicated  crack  growth  di-
                  rection – from the centre of each specimen to its edge. It is derived from the compari-
                  son of the presented fracture maps that, despite of the appearance of TTS (which is ac-
                  tually tiny comparing to the whole fracture surface) and crack origin from the lateral
                  surface,  fracture  under  cathodic  polarization  is  suggested  to  be  quasi  symmetrical.
                  Therefore  the  tendency  of  RA changes  due  to  cold  drawing  is  similar  in  air  and  in
                  hydrogenating conditions.
                      CONCLUSION
                      Division of the values of reduction in area as a basic plasticity parameter of steel
                  into the components responsible for crack initiation and crack growth allows one to
                  consider  the  stage of  crack  initiation  and  crack  propagation  separately.  It  should  be
                  noted that a tendency of its changes with strain increment e are similar for both test
                  conditions, in particular, increase of susceptibility to crack initiation and simultaneous
                  improvement of resistance to crack propagation in heavily drawn steels.


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